Tunable Phonon Polariton Hybridization in a van der Waals Hetero-Bicrystal.

Phonon polaritons, the hybrid quasiparticles resulting from the coupling of photons and lattice vibrations, have gained significant attention in the field of layered van der Waals heterostructures. Particular interest has been paid to hetero-bicrystals composed of molybdenum oxide (MoO3) and hexagonal boron nitride (hBN), which feature polariton dispersion tailorable via avoided polariton mode crossings. In this work, we systematically study the polariton eigenmodes in MoO3-hBN hetero-bicrystals self-assembled on ultrasmooth gold using synchrotron infrared nanospectroscopy. We experimentally demonstrate that the spectral gap in bicrystal dispersion and corresponding regimes of negative refraction can be tuned by material layer thickness, and we quantitatively match these results with a simple analytic model. We also investigate polaritonic cavity modes and polariton propagation along "forbidden" directions in our microscale bicrystals, which arise from the finite in-plane dimension of the synthesized MoO3 micro-ribbons. Our findings shed light on the unique dispersion properties of polaritons in van der Waals heterostructures and pave the way for applications leveraging deeply sub-wavelength mid-infrared light matter interactions. This article is protected by copyright. All rights reserved.

Ultrastrong exciton-plasmon couplings in WS2 multilayers synthesized with a random multi-singular metasurface at room temperature.

Van der Waals semiconductors exemplified by two-dimensional transition-metal dichalcogenides have promised next-generation atomically thin optoelectronics. Boosting their interaction with light is vital for practical applications, especially in the quantum regime where ultrastrong coupling is highly demanded but not yet realized. Here we report ultrastrong exciton-plasmon coupling at room temperature in tungsten disulfide (WS2) layers loaded with a random multi-singular plasmonic metasurface deposited on a flexible polymer substrate. Different from seeking perfect metals or high-quality resonators, we create a unique type of metasurface with a dense array of singularities that can support nanometre-sized plasmonic hotspots to which several WS2 excitons coherently interact. The associated normalized coupling strength is 0.12 for monolayer WS2 and can be up to 0.164 for quadrilayers, showcasing the ultrastrong exciton-plasmon coupling that is important for practical optoelectronic devices based on low-dimensional semiconductors.

Chiral transmission by an open evolution trajectory in a non-Hermitian system.

Exceptional points (EPs), at which two or more eigenvalues and eigenstates of a resonant system coalesce, are associated with non-Hermitian Hamiltonians with gain and/or loss elements. Dynamic encircling of EPs has received significant interest in recent years, as it has been shown to lead to highly nontrivial phenomena, such as chiral transmission in which the final state of the system depends on the encircling handedness. Previously, chiral transmission for a pair of eigenmodes has been realized by establishing a closed dynamical trajectory in parity-time- (PT-) or anti-PT-symmetric systems. Although chiral transmission of symmetry-broken modes, more accessible in practical photonic integrated circuits, has been realized by establishing a closed trajectory encircling EPs in anti-PT-symmetric systems, the demonstrated transmission efficiency is very low due to path-dependent losses. Here, we demonstrate chiral dynamics in a coupled waveguide system that does not require a closed trajectory. Specifically, we explore an open trajectory linking two infinite points having the same asymptotic eigenmodes (not modes in PT- and anti-PT-symmetric systems), demonstrating that this platform enables high-efficiency chiral transmission, with each eigenmode localized in a single waveguide. This concept is experimentally implemented in a coupled silicon waveguide system at telecommunication wavelengths. Our work provides a new evolution strategy for chiral dynamics with superior performance, laying the foundation for the development of practical chiral-transmission devices.

Metasurface-Based Optical Logic Operators Driven by Diffractive Neural Networks.

In this paper, a novel optical logic operator based on the multifunctional metasurface driven by all-optical diffractive neural network is reported, which can perform four principal quantum logic operations (Pauli-X, Pauli-Y, Pauli-Z, and Hadamard gates). The two ground states | 0 ⟩ $|0 \rangle $ and | 1 ⟩ $|1 \rangle $  are characterized by two orthogonal linear polarization states. The proposed spatial- and polarization-multiplexed all-optical diffractive neural network only contains a hidden layer physically mapped as a metasurface with simple and compact unit cells, which dramatically reduces the volume and computing resources required for the system. The designed optical quantum operator is proven to achieve high fidelities for all four quantum logical gates, up to 99.96% numerically and 99.88% experimentally. The solution will facilitate the construction of large-scale optical quantum computing systems and scalable optical quantum devices.

Hyperbolic Polaritonic Rulers Based on van der Waals α-MoO3 Waveguides and Resonators.

Low-dimensional, strongly anisotropic nanomaterials can support hyperbolic phonon polaritons, which feature strong light-matter interactions that can enhance their capabilities in sensing and metrology tasks. In this work, we report hyperbolic polaritonic rulers, based on microscale α-phase molybdenum trioxide (α-MoO3) waveguides and resonators suspended over an ultraflat gold substrate, which exhibit near-field polaritonic characteristics that are exceptionally sensitive to device geometry. Using scanning near-field optical microscopy, we show that these systems support strongly confined image polariton modes that exhibit ideal antisymmetric gap polariton dispersion, which is highly sensitive to air gap dimensions and can be described and predicted using a simple analytic model. Dielectric constants used for modeling are accurately extracted using near-field optical measurements of α-MoO3 waveguides in contact with the gold substrate. We also find that for nanoscale resonators supporting in-plane Fabry-Perot modes, the mode order strongly depends on the air gap dimension in a manner that enables a simple readout of the gap dimension with nanometer precision.

Impact of Ocean Acidification on the Gut Histopathology and Intestinal Microflora of Exopalaemon carinicauda.

Marine crustaceans are severely threatened by environmental factors such as ocean acidification, but, despite the latter's negative impact on growth, molting, and immunity, its effects on intestinal microflora remain poorly understood. This work studied the gut morphology and intestinal microflora of Exopalaemon carinicauda, grown in seawater of different pH levels: 8.1 (control group), 7.4 (AC74 group), and 7.0 (AC70 group). Ocean acidification was found to cause intestinal damage, while significantly altering the microflora's composition. However, the α-diversity did not differ significantly between the groups. At the phylum level, the relative abundance of Proteobacteria decreased in the acidification groups, while at the genus level, the relative abundance of Sphingomonas decreased. Babeliales was a prominent discriminative biomarker in the AC74 group, with Actinobacteriota, Micrococcales, Beijerinckiaceae, Methylobacterium, and Flavobacteriales being the main ones in the AC70 group. The function prediction results also indicated an enrichment of pathways related to metabolism for the acidification groups. At the same time, those related to xenobiotics' biodegradation and metabolism were inhibited in AC74 but enhanced in AC70. This is the first study examining the impact of ocean acidification on the intestinal microflora of crustaceans. The results are expected to provide a better understanding of the interactions between shrimp and their microflora in response to environmental stressors.

Interfacial Compatibility of Core-Shell Cellulose Nanocrystals for Improving Dynamic Covalent Adaptable Networks' Fracture Resistance in Nanohybrid Vitrimer Composites.

The development of polymeric nanocomposites with dynamic covalent adaptable networks and biobased nanomaterials has been a promising approach toward sustainable advanced materials, enabling reprogramming and recycling capabilities. Herein, a core-shell nanohybrid of functionalized cellulose nanocrystals (CNCs) is explored to provide crucial interfacial compatibility for improving the covalent adaptable networks of epoxy-thiol vitrimers in fracture resistance. The poly(ε-caprolactone) (PCL) shells grafted from CNC surfaces can be cross-linked with the covalent adaptable networks via a hot-pressing transesterification process. According to the additive concentration and annealing temperature, the stress relaxation behavior of nanohybrid vitrimer composites can be effectively regulated by the core-shell PCL-grafted CNC (CNC-PCL) nanohybrids from a dispersed to cross-linked interaction. The addition of 15 wt % of the core-shell CNC-PCLs exhibits the reinforced improvement of nanohybrid vitrimer composites in the average Young's modulus of 2.5×, fracture stress of 5.4×, and fracture strain of 2.0×. The research findings might have profound implications for developing synergistic interfacial compatibility between dynamic vitrimer networks and functional nanoparticles for advanced polymeric nanocomposites.

Continuous programmable mid-infrared thermal emitter and camouflage based on the phase-change material In3SbTe2.

In3SbTe2 (IST), a new non-volatile phase-change material (PCM), promises highly tunable infrared optical properties and offers a distinct path to the significant modulation of its optical scattering fingerprint, suggesting tremendous applications. In this Letter, we demonstrate and optimize a four-layer emitter based on IST, achieving an ultra-wide average emissivity variation of more than 94% in the middle-infrared region (MIR, 3-5 µm). This remarkable emissivity difference can be further continuously modified by changing the structural composition in terms of the amorphous and crystalline states of the IST layers. Based on this continuous programmable emission, the MIR emission characteristics of marble, maple leaf, and blue polyvinyl chloride are successfully imitated together on a desert background, demonstrating the programmable and multi-level MIR optical camouflage capabilities of IST. This work provides a promising platform for continuously modulating emission characteristics and offers a reference for the subsequent application of programmable optical devices.

Hyperbolic polaritonic crystals with configurable low-symmetry Bloch modes.

Photonic crystals (PhCs) are a kind of artificial structures that can mold the flow of light at will. Polaritonic crystals (PoCs) made from polaritonic media offer a promising route to controlling nano-light at the subwavelength scale. Conventional bulk PhCs and recent van der Waals PoCs mainly show highly symmetric excitation of Bloch modes that closely rely on lattice orders. Here, we experimentally demonstrate a type of hyperbolic PoCs with configurable and low-symmetry deep-subwavelength Bloch modes that are robust against lattice rearrangement in certain directions. This is achieved by periodically perforating a natural crystal α-MoO3 that hosts in-plane hyperbolic phonon polaritons. The mode excitation and symmetry are controlled by the momentum matching between reciprocal lattice vectors and hyperbolic dispersions. We show that the Bloch modes and Bragg resonances of hyperbolic PoCs can be tuned through lattice scales and orientations while exhibiting robust properties immune to lattice rearrangement in the hyperbolic forbidden directions. Our findings provide insights into the physics of hyperbolic PoCs and expand the categories of PhCs, with potential applications in waveguiding, energy transfer, biosensing and quantum nano-optics.

What do Retraction Notices Reveal About Institutional Investigations into Allegations Underlying Retractions?

Academic journal publications may be retracted following institutional investigations that confirm allegations of research misconduct. Retraction notices can provide insight into the role institutional investigations play in the decision to retract a publication. Through a content analysis of 7,318 retraction notices published between 1927 and 2019 and indexed by the Web of Science, we found that most retraction notices (73.7%) provided no information about institutional investigations that may have led to retractions. A minority of the retraction notices (26.3%) mentioned an institutional investigation either by journal authorities (12.1%), research performing organizations (10.3%), joint institutions (1.9%), research integrity and ethics governing bodies (1.0%), third-party institutions (0.5%), unspecified institutions (0.4%), or research funding organizations (0.1%). Comparing retraction notices issued before and after the introduction of retraction guidelines by the Committee on Publication Ethics (COPE) in 2009 revealed that those published after the guidelines' publication were more likely to report investigations by journal authorities. Comparing retraction notices from different disciplines revealed that those from social sciences and the humanities were more likely to disclose investigations by research performing organizations than those from biomedical and natural sciences. Based on these findings, we suggest that the COPE retraction guidelines in the future make it mandatory to disclose in retraction notices institutional investigations leading to retractions.

Twist-Angle and Thickness-Ratio Tuning of Plasmon Polaritons in Twisted Bilayer van der Waals Films.

Stacking bilayer structures is an efficient way to tune the topology of polaritons in in-plane anisotropic films, e.g., by leveraging the twist angle (TA). However, the effect of another geometric parameter, the film thickness ratio (TR), on manipulating the plasmon topology in bilayers is elusive. Here, we fabricate bilayer structures of WTe2 films, which naturally host in-plane hyperbolic plasmons in the terahertz range. Plasmon topology is successfully modified by changing the TR and TA synergistically, manifested by the extinction spectra of unpatterned films and the polarization dependence of the plasmon intensity measured in skew ribbon arrays. Such TR- and TA-tunable topological transitions can be well explained based on the effective sheet optical conductivity by adding up those of the two films. Our study demonstrates TR as another degree of freedom for the manipulation of plasmonic topology in nanophotonics, exhibiting promising applications in biosensing, heat transfer, and the enhancement of spontaneous emission.

Mold-free self-assembled scalable microlens arrays with ultrasmooth surface and record-high resolution.

Microlens arrays (MLAs) based on the selective wetting have opened new avenues for developing compact and miniaturized imaging and display techniques with ultrahigh resolution beyond the traditional bulky and volumetric optics. However, the selective wetting lenses explored so far have been constrained by the lack of precisely defined pattern for highly controllable wettability contrast, thus limiting the available droplet curvature and numerical aperture, which is a major challenge towards the practical high-performance MLAs. Here we report a mold-free and self-assembly approach of mass-production of scalable MLAs, which can also have ultrasmooth surface, ultrahigh resolution, and the large tuning range of the curvatures. The selective surface modification based on tunable oxygen plasma can facilitate the precise pattern with adjusted chemical contrast, thus creating large-scale microdroplets array with controlled curvature. The numerical aperture of the MLAs can be up to 0.26 and precisely tuned by adjusting the modification intensity or the droplet dose. The fabricated MLAs have high-quality surface with subnanometer roughness and allow for record-high resolution imaging up to equivalently 10,328 ppi, as we demonstrated. This study shows a cost-effective roadmap for mass-production of high-performance MLAs, which may find applications in the rapid proliferating integral imaging industry and high-resolution display.

Characterization of a crustin-like peptide involved in shrimp immune response to bacteria and Enterocytozoon hepatopenaei (EHP) infection in Palaemon carinicauda.

Crustins represent one type of antimicrobial peptides (AMPs) that are key components of the innate immune process of crustaceans. This study successfully identified a novel crustin-like peptide, EcCrustin2, in ridgetail white prawn, Palaemon carinicauda (formerly Exopalaemon carinicauda). EcCrustin2 was found to be 1082 bp in length, with a 378 bp open reading frame (ORF) encoding 125 amino acids. The deduced amino acid sequence of EcCrustin2 exhibited characteristics of crustins in crustacean, including a Cys-rich region at the N-terminus as well as a whey acidic protein domain at the C-terminus. Phylogenetic analysis revealed that the EcCrustin2 was first clustered with Type I crustins, then with other crustins. Expression of EcCrustin2 was mainly detected in immune tissues, including hemocytes, gill and stomach. The expression level of EcCrustin2 was also significantly up-regulated after being exposed to lipopolysaccharide (LPS), lipoteichoic acid (LTA), Vibrio parahaemolyticus and Staphylococcus aureus. EHP infection could also induce EcCrustin2 expression in P. carinicauda. Knockdown of EcCrustin2 with siRNA increased the mortality of V. parahaemolyticus challenged shrimp. Finally, the recombinant EcCrustin2 protein was obtained and demonstrated a wide spectrum of antibacterial activity in vitro. These results indicated that EcCrustin2 takes part in the immune response against bacteria and EHP infection.

Single-shot isotropic differential interference contrast microscopy.

Differential interference contrast (DIC) microscopy allows high-contrast, low-phototoxicity, and label-free imaging of transparent biological objects, and has been applied in the field of cellular morphology, cell segmentation, particle tracking, optical measurement and others. Commercial DIC microscopy based on Nomarski or Wollaston prism resorts to the interference of two polarized waves with a lateral differential offset (shear) and axial phase shift (bias). However, the shear generated by these prisms is limited to the rectilinear direction, unfortunately resulting in anisotropic contrast imaging. Here we propose an ultracompact metasurface-assisted isotropic DIC (i-DIC) microscopy based on a grand original pattern of radial shear interferometry, that converts the rectilinear shear into rotationally symmetric along radial direction, enabling single-shot isotropic imaging capabilities. The i-DIC presents a complementary fusion of typical meta-optics, traditional microscopes and integrated optical system, and showcases the promising and synergetic advancements in edge detection, particle motion tracking, and label-free cellular imaging.

Moisture-Tailored 2D Dion-Jacobson Perovskites for Reconfigurable Optoelectronics.

Humidity- and moisture-induced degradation has been a longstanding problem in perovskite materials, affecting their long-term stability during applications. Counterintuitively, the moisture is leveraged to tailor the reversible hydrochromic behaviors of a new series of 2D Dion-Jacobson (DJ) perovskites for reconfigurable optoelectronics. In particular, the hydrogen bonds between organic cations and water molecules can be dynamically modulated via moisture removal/exposure. Remarkably, such modulation confines the movement of the organic cations close to the original position, preventing their escape from crystal lattices. Furthermore, this mechanism is elucidated by theoretical analysis using first-principles calculations and confirmed with the experimental characterizations. The reversible fluorescent transition 2D DJ perovskites show excellent cyclical properties, presenting untapped opportunities for reconfigurable optoelectronic applications. As a proof-of-concept demonstration, an anti-counterfeiting display is shown based on patterned reversible 2D DJ perovskites. The results represent a new avenue of reconfigurable optoelectronic application with 2D DJ perovskites for humidity detection, anti-counterfeiting, sensing, and other emerging photoelectric intelligent technologies.

Super-reflector enabled by non-interleaved spin-momentum-multiplexed metasurface.

Electromagnetic wave multiplexing, especially for that occurring at different incidences (spatial-frequency multiplexing), is pivotal for ultrathin multifunctional interfaces and high-capacity information processing and communication. It is yet extremely challenging based on passive and compact wave elements, since the wave excitation and scattering channels are exclusively coupled through gradient phases and hence momentum matching condition at the interface. Here, we propose a spin-momentum multiplexed paradigm called a super-reflector enabling on-demand control of both retroreflections and anomalous reflections using a non-interleaved single-celled metasurface. By multiplexing four channels connecting two spin states excited onto each input of three spatial frequencies, a total of twelve channels are engineered, among which three are retroreflected channels and the residual are anomalous reflection ones. Our compound multiplexed super-reflector allows five degrees of freedom in circular polarization Jones' matrix, approaching the intrinsic upper limit of such planar metasurface. The concept has been experimentally verified by a proof-of-concept super-reflector at microwave frequency, showcasing twelve reflected beams and a high efficiency exceeding 90.6% defined as the ratio of reflected power to incidence for each channel beam. Our strategy opens a new avenue for angle multiplexing and angle-resolved metadevices toward the capacity limit of 2D planar Jones' matrix.

Challenges for enforcing editorial policies on AI-generated papers.

ChatGPT, a chatbot released by OpenAI in November 2022, has rocked academia with its capacity to generate papers "good enough" for academic journals. Major journals such as Nature and professional societies such as the World Association of Medical Editors have moved fast to issue policies to ban or curb AI-written papers. Amid the flurry of policy initiatives, one important challenge seems to be overlooked: AI-generated papers are not easily discernible to the human eye, and we lack the right tools to implement the policies. Without such tools, the well-intentioned policies are likely to remain on paper.

Isolation and characterization of an algicidal bacterium against the bloom-forming algae raphidophyte Heterosigma akashiwo.

Harmful algae blooms (HABs) have increased in intensity and frequency worldwide, causing negative effects on public health and marine ecosystems. This study isolated and identified the bloom causing species and its associated algicidal bacterium during a phytoplankton bloom in coastal waters of Lianyungang, China. Morphological observations and DNA barcoding analysis indicate that the studied phytoplankton bloom was caused by the raphidophyte Heterosigma akashiwo, and the algicidal bacterium, strain LD-B1, was identified as a species belonging to the genus Pseudoalteromonas. Furthermore, the algicidal effects of strain LD-B1 against H. akashiwo were characterized; revealing strain LD-B1 show strong algicidal activity against H. akashiwo. After 48 h of bacterium culture addition, the algicidal rate reached up to 98.8% with a 1% final volume rate. Moreover, our findings indicate strain LD-B1's extracellular compounds involved in algicidal activity are likely not proteinaceous. These findings indicate that the isolated strain, LD-B1, is a promising algicidal bacterium to control H. akashiwo blooms.